Kharlampieva Research Group


    Department of Chemistry, University of Alabama at Birmingham
    901 14th Street South CHEM291, Birmingham, AL 35294

Previous Publications
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B. Wallet, E. Kharlampieva, K. L. Campbell-Proszowska, V. Kozlovskaya, S. Malak, J. F. Ankner, D. L. Kaplan, V. V. Tsukruk, Silk layering as studied with neutron reflectivity, Langmuir 2012, 28, 11481-11489.

  41. J. T. Wilson, W. Cui, V. Kozlovskaya, E. Kharlampieva, D. Pan, Z. Qu, V. R. Krishnamurthy, J. Mets, V. Kumar, J. Wen, Y. Song, V. Tsukruk, E. L. Chaikof, Cell surface engineering with polyelectrolyte multilayer thin films, J. Am. Chem. Soc. 2011, 133, 7054-7064.
  40. S.T. Krishnaji, W. Huang, O. Rabotyagova, E. Kharlampieva, I. Choi, V. Tsukruk, R. Naik, P. Cebe, D. L. Kaplan,  Thin film assembly of Spider Silk-like block copolymers, Langmuir 2011, 27, 1000-1008.
  39. E. Kharlampieva, V. Kozlovskaya, B. Wallet, V. V. Shevchenko, R. R. Naik, R. Vaia, D. L. Kaplan, V. V. Tsukruk, Robust silk-inorganic nanocomposite membranes: silica nanoparticles vs clay nanoplatelets, ACS Nano 2010, 4, 7053-7063.
  38. E. Kharlampieva, V. Kozlovskaya, R. Gunawidjaia, V. V. Shevchenko, D. Kaplan, R. Vaia, R. R. Naik, V. V. Tsukruk, Reinforced natural nanocomposites based on silk matrices: From highly transparent to mirror-like flexible, Adv. Func. Mater. 2010, 20, 840-846.
  37. O. Shchepelina, V. Kozlovskaya, E. Kharlampieva, W. Mao, A. Alexeev, V. V. Tsukruk, Cubic and tetrahedral anisotropic hollow micro- and submicron capsules based on tannic acid, Macromol. Rapid  Comm. 2010, 31, 2041-2046.
  36. E. Kharlampieva, C. M. Jung, V. Kozlovskaya, V. V. Tsukruk, Secondary structure of silaffin at interfaces and titania formation, J. Mater. Chem. 2010, 20,  5242-5250.
  35. V. Kozlovskaya, E. Kharlampieva, K. Jones, Z. Li, V. V. Tsukruk, pH-Controlled assembly and properties of LbL membranes from branched conjugated poly(alkoxythiophene sulfonate) and various polycations, Langmuir 2010, 26, 7138-7147.
  34. E. Kharlampieva, V. Kozlovskaya, O. Zavgorodnya, G. D. Lilly, N. A. Kotov, V. V. Tsukruk, Thin films for confined incorporation of quantum dot optical markers, Soft Matter 2010, 6, 800-807.
  33.  S. Singamaneni, E. Kharlampieva, J.-H. Jang, M. E. McConney, H. Jiang, T.J.Bunning, E. L. Thomas, V. V. Tsukruk, Metallized porous interference lithographic microstructures via biofunctionalization, Adv. Mater. 2010, 22, 1369-1373.
  32.  V. Kozlovskaya, E. Kharlampieva, I. Drachuk, D. Cheng, V. V. Tsukruk, Responsive microcapsule reactors based on hydrogen-bonded tannic acid layer-by-layer assemblies, Soft Matter 2010, 6, 3596-3608.
  31.  V. H. Orozco, V. Kozlovskaya, E. Kharlampieva, B. L. López, V. V. Tsukruk, Biodegradable composite assemblies of PLA nanoparticles engineered layer-by-layer, Polymer 2010, 51, 4127-4139.
  30. O. Shchepelina, V. Kozlovskaya, S. Singamaneni, E. Kharlampieva, V. V. Tsukruk, Anisotropic mesoscale replicas from organic, inorganic, and biological templates, J. Mater. Chem. 2010, 20, 6587-6603.
  29. E. Kharlampieva, V. V. Tsukruk, Unmasked by Stretching, Nat. Mater. 2009, 8, 704-705.
  28.  E. Kharlampieva, V. Kozlovskaya, J. Chan, J. F. Ankner, V. V. Tsukruk, Spin-assisted layer-by-layer assembly: Variation of stratification as studied with neutron reflectivity, Langmuir 2009, 25, 14017-14024. (Invited Paper to Langmuir 25th-year special issue).
  27.  V. Kozlovskaya, E. Kharlampieva, I. Erel-Unal, S. A. Sukhishvili, Multilayer-derived, ultrathin, stimuli-responsive hydrogels, Soft Matter 2009, 5, 4077-4087 (Invited Review).
  26.  R. Gunawidjaja, E. Kharlampieva, I. Choi, V. V. Tsukruk, Bimetallic nanostructures as active Raman markers: gold nanoparticles assembly on 1D and 2D silver nanostructures surface, Small 2009, 5, 2460-2466.
  25.  S. Chang, S. Singamaneni, E. Kharlampieva, S. Chang, V. V. Tsukruk, Responsive hybrid nanotubes composed of block copolymers and gold nanoparticles, Macromolecules 2009, 42, 5781-5785.
  24.  E. Kharlampieva, D. Zimnitsky, M. Gupta, K. N. Bergman, D. L.  Kaplan, R. R. Naik, V. V. Tsukruk, Redox-active ultrathin template of silk fibroin: effect of conformation on gold nanoparticle reduction, Chem. Mater. 2009, 21, 2696-2704.
  23.  V. Kozlovskaya, E. Kharlampieva,  S. Chang, R. Muhlbauer, V.V. Tsukruk, pH-Responsive layered hydrogel microcapsules as gold nanoreactors, Chem. Mater. 2009, 21, 2158-2167.
  22.  E. Kharlampieva, J. M. Slocik, S. Singamaneni, N. Poulsen, N. Kroger, R. R. Naik, V. V. Tsukruk, Protein-induced synthesis of monodisperse titania nanoparticles on and within polyelectrolyte matrices, Adv. Func. Mater. 2009, 19, 2303-2311.
  21.  E. Kharlampieva, V. Kozlovskaya, S. A. Sukhishvili, Layer-by-layer hydrogen-bonded polymer films: From fundamentals to applications, Adv. Mater. 2009, 21, 3053-3065 (Invited Progress Report).
  20.  V. Kozlovskaya, E. Kharlampieva, I. Erel-Unal, S. A. Sukhishvili, Single-component layer-by-layer weak polyelectrolyte films and capsules: Loading and release of functional molecules, Polymer Science Series A: Chemistry Physics 2009, 51, 719-729 (Invited Paper).
  19.  E. Kharlampieva, J. F. Ankner, M. Rubinstein, S. A. Sukhishvili, pH-Induced release of polyanions from multilayer films, Phys. Rev. Lett. 2008, 100, 128303.
  18.  E. Kharlampieva, T. Tsukruk, J. M. Slocik, H. Ko, N. Poulsen, R. R. Naik, N. Kroger, V. V. Tsukruk, Bioenabled surface-mediated growth of  titania nanoparticles,  Adv. Mater. 2008, 20, 3274-3279.
  17.  E. Kharlampieva, V. Kozlovskaya, J. F. Ankner, S. A. Sukhishvili, Hydrogen-bonded polymer multilayers probed by neutron reflectivity, Langmuir 2008, 24, 11346-11349.
  16.  V. Kozlovskaya, E. Kharlampieva, B. P. Khanal, P. Manna, E. R. Zubarev, V. V. Tsukruk, Ultrathin layer-by-layer hydrogels with incorporated gold nanorods as pH-sensitive optical materials, Chem. Mater. 2008, 20, 7474-7485.
  15.  E. Kharlampieva, J. M. Slocik, H. Ko, T. Tsukruk , R. R. Naik, V. V. Tsukruk, Polyaminoacid-induced growth of metal nanoparticles on layer-by-layer templates, Chem. Mater. 2008, 20, 5822-5831.
  14.  E. Kharlampieva, D. Pristinski, S. A. Sukhishvili, Hydrogen-bonded multilayers of poly(carboxybetaine), Macromolecules 2007, 40, 6967-6972.
  13.  E. Kharlampieva, V. Izumrudov, S. A. Sukhishvili, Electrostatic layer-by-layer self-assembly of poly(carboxybetaine)s: Role of zwitterions in film growth, Macromolecules 2007, 40, 3663-3668.
  12.  E. Kharlampieva, I. Erel-Unal, S. A. Sukhishvili, Amphoteric surface hydrogels derived from hydrogen-bonded multilayers: Reversible loading of dyes and proteins, Langmuir 2007, 23, 175-181 (Invited Paper).
  11.  S. A. Sukhishvili, E. Kharlampieva, V. Izumrudov, Where polyelectrolyte multilayers and polyelectrolyte complexes meet, Macromolecules 2006, 39, 8873-8881.
  10.  E. Kharlampieva, S. A. Sukhishvili, Hydrogen-bonded layer-by-layer polymer films, Journal of Macromolecular Science, Part C: Polymer Reviews 2006, 46, 377-395 (Invited Review).
  9.  V. Kozlovskaya, E. Kharlampieva, M. L. Mansfield, S. A. Sukhishvili, Poly(methacrylic acid) hydrogel films and capsules: Response to pH and ionic strength, and encapsulation of macromolecules, Chem. Mater. 2006, 18, 328-336.
8.  E. Kharlampieva, V. Kozlovskaya, J. Tyutina, S. A. Sukhishvili, Hydrogen-bonded multilayers of thermoresponsive polymers, Macromolecules 2005, 38, 10523-10531.
  7.  V. Izumrudov, E. Kharlampieva, S. A. Sukhshvili, Multilayers of a globular protein and a weak polyacid: Role of polyacid ionization in growth and decomposition in salt solutions, Biomacromolecules 2005, 6, 1782-1788.
  6.  E. Kharlampieva, S. A. Sukhishvili, Release of a dye from hydrogen-bonded and electrostatically assembled polymer films triggered by adsorption of a polyelectrolyte, Langmuir 2004, 20, 9677-9685.
  5.  E. Kharlampieva, S. A. Sukhishvili, Competition of hydrogen-bonding and electrostatic interactions within hybrid polymer multilayers, Langmuir 2004, 20, 10712-10717.
  4.  V. Izumrudov, E. Kharlampieva, S. A. Sukhishvili, Salt-induced multilayer growth: Correlation with phase separation in solution, Macromolecules 2004, 37, 8400-8406.
  3.  E. Kharlampieva, S. A. Sukhishvili, Polyelectrolyte multilayers of weak polyacid and cationic copolymer: Competition of hydrogen bonding and electrostatic interactions, Macromolecules 2003, 36, 9950-9956.
  2.  E. Kharlampieva, S. A. Sukhishvili, Ionization and pH-stability of multilayers formed by self-assembly of weak polyelectrolytes, Langmuir 2003, 19, 1235-1243.
  1.  D. G. Kim, V. I. Shmygarev, E. P. Kharlampieva, D. V. Vorob'ev, Synthesis and properties of 2-(styrylthio)pyrimidin-6(1H)-ones, Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii) 1997, 33, 1341.
Book Chapters & Highlights
V. Kozlovskaya, E. Kharlampieva, S.A. Sukhishvili, Hydrogen-bonded layer-by-layer films and capsules, in Hydrogen-bonded interpolymer complexes: Formation, Structure and Applications, V.V. Khutoryanskiy, G. Staikos, Eds., World Scientific Publishing Company PTE LTD, 2009, 323-362.
J. F. Ankner, X. Tao, C.E. Halbert, J. F. Browning, S. Michael Kilbey II, O. A. Swader, M. S. Dadmun, E. Kharlampieva and S. A. Sukhishvili, SNS Liquid Reflectometer, Neutron News 2008, 19, 14.
Patent Applications
Capsules of multilayered neutral polymer films associated by hydrogen bonding. Sukhishvili, S. A., Kozlovskaya, V., Kharlampieva, E. (2005).
Methods for controlled release of molecules from layered polymer films.   Sukhishvili, S. A., Kharlampieva, E., Izumrudov, V. A. (2004). 

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